Once the dangerous part of the launch is over.
The first thing the spacecraft has to do it to get into orbit by riding on top of a huge rocket. This is very dangerous as rockets are known do spontaneously explode on occasion (as you would expect from a vehicle made of 98% fuel and riding a explosion at 10 times the speed of sound).
Once into orbit and clear of the rocket the risk of an accident requiring a helmet becomes basically 0.
**[edit]** They’ll have to put their suit and helmet back when approaching the space station, because it is also dangerous (the main risk is a loss of control and collision with the station)
**[edit]** For those confused: the helmet isn’t here to protect them from an explosion directly, but from the potential decompression that comes with a failure of the vehicle and/or the violent shaking and acceleration that happen in an abort scenario.
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