Some numbers we give special names.
For instance, the number 12 is called a dozen. The reason 12 gets a special name it is a commonly used number and places like bakeries adopted it usage.
Similarly, Avogadro came up with a really useful number that simplifies communicating about large numbers of atoms and molecules. Instead of saying I have 100,000,000,000,000,000,000,000 molecules of water, you can say I have 0.17 mol of water. It’s just an easier way to speak and write.
It’s the same reason astronomers use light years and not feet or meters.
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