Your asphalt roof of your carport probably gets colder than ambient on most cloudless nights. Black body radiation is a thing and that dark roof with no heat source underneath will probably continue to radiate energy.
Here is how people used to create ice in above zero conditions for thousands of years.
https://www.realclearscience.com/blog/2018/07/09/how_people_created_ice_in_the_desert_2000_years_ago.html
So the answer is absolutely yes objects can get colder than ambient.
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