If you burn wood, the majority of the carbon is released, mostly as carbon dioxide and a little carbon monoxide. Some remains as ash.
When wood decomposes, microorganisms release some of the carbon as gases, mostly carbon dioxide and methane. Unlike burning, however, more of the carbon is incorporated into organism doing the decomposition, and some is lost as waste products to the environment.
Decomposition keeps a higher percentage bound up for longer, but it’s all part of a global cycle. Pretty much all carbon on the surface will be carbon in the air for a while, then eventually work it’s way back into plants and other living things.
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