The voltage of the most common battery chemistries is proportional to the charge level. The battery loses strength as it’s getting discharged. The device has a regulator in it that draws more current to allow it to operate normally. With other types of cells like NiMH it doesn’t work. The charger could place a constant dummy load on it, and measure the time until the battery is flat.
Every electrical device has a upper and lower limit in terms of voltage where it can correctly operate. For example your RC car might be designed to use a 12v battery(the battery is at 12v when fully charged), but if for example the battery drops to 8v because of use the car it will not be able to run due to lack of power. In this example you have 4v of power you can “use” which corresponds to a percentage. Batteries can track consumption non-linearly which means 10v might not be 50% but instead 15%.
Note: The current(amps) of a battery doesn’t change because it measures the quantity of electrons in the battery. If will not change unless electricity is being routed the wrong way to the ground instead back to the battery.
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