Eli5, How do we know a molecules’s shape?

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I was reading the other post about H2O vs H2O2, and someone mentioned that H2O2 is structured like HOOH. How do we know this? Why not OHHO? Is it process of elimination from knowing that certain atoms don’t form bonds in a certain way?

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Anonymous 0 Comments

Hydrogen’s electron cloud only has one “connector” for bonding. Oxygen has two.

More specifically, hydrogen’s electron cloud is one electron away from full, while oxygen’s is two. Atoms don’t like to have partially filled electron clouds, and will try to complete them. In the case of hydrogen and oxygen, this means bonding.

When two atoms bond, they each share two electrons, one from each. But, each electron in the bond takes up space in both atoms’ electron clouds. So, forming a bond adds an electron to both atoms’ electron clouds.

Hydrogen bonds with oxygen, and it’s full. But, the oxygen still has one unfilled slot, so it can bond to one more atom. This can be another hydrogen (in the case of water), another oxygen (in the case of hydrogen peroxide), or whatever.

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