There is a neurotransmitter called Adenosine that is responsible for making us feel sleepy. This accumulates throughout the day. While you sleep, it is metabolized/ broken down by the body until the levels of it are low enough that your brain stops being sleepy.
There is also a hormone called Melatonin that regulates the rise and fall of your circadian rhythm. This is what keeps your body on a natural schedule, assuming no interruptions from artificial light and alarm clocks…etc
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