Lightning produces light due to a process called incandescence. Essentially, when lightning comes down it creates a channel of conductive plasma within the air. The heat flow within this channel heats up the air rapidly to about 50,000 degrees fahrenheit. These air temperatures cause a process called incandescence to the point where the molecules in the air emit light.
Sunlight works differently as in it’s a portion of the electromagnetic radiation given off by the sun, in particular infrared, ultraviolet, and visible light.
TLDR; Lightning produces light through the rapid heating of air molecules, where as sunlight comes from sun radiation.
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