Bitter substances can help aid digestion by stimulating production of stomach acids. In Europe, there are a whole slew of bitter beverages to aid digestion. Italians call them “digestivi” Fernet Branca is a popular example.
Other bitter substances (like salicylic acid from the willow tree) prevent inflammation in people and aid with pain management – salicylic acid is the precursor to aspirin.
So, tl;dr bitter substances have been found useful to humans so have been widely adopted.
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