Volcanoes throw a lot of rock, dust, ash and other crap into the atmosphere. These block sunlight from getting to earth’s surface, which reduces global temperatures. The loss of sunlight also adversely affects plant growth (see 1816: the year without a summer)
It’s suspected that if the Yellowstone supervolcano were to erupt then it would make the northern hemisphere almost completely uninhabitable and cut global temperatures by 20°C, triggering a short ice age.
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