In a basic world, YES.
In a slightly more complicated world with wind resistance, YES, RELATIVE TO THE GROUND, ASSUMING HE THREW IT IN THE DIRECTION THE TRAIN WAS GOING, but it immediately starts slowing down.
In a massively more complicated (but technically more accurate) world, it’s going about 149.9999999999 mph.
Due to relativity, speeds don’t sum linearly.
Feel free to ask questions if you have them.
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