Technically? Yes
Usefully? No
[Betavoltaics](https://en.wikipedia.org/wiki/Betavoltaic_device) are a thing where you put a strong beta emitter inside the right materials and capture the electrons(Beta particles) that it throws off and use that to generate power. They’re not good for anything but tiny tiny power sources. There are some that exist for pacemakers but a “high powered” beta voltaic source will generate 100 uW
Gammavoltaic cells have been considered but not built. Gamma rays are really hard to collect, they just ignore most things
One of the big components of spent nuclear fuel is Caesium-137 which has a half life of 30 years making it quite radioactive. When it decays it gives off a Beta particle with about 0.5 MeV of energy and a Gamma ray with 0.66 MeV for a total of 1.1 MeV of energy which isn’t zero but isn’t a ton.
When you fission a single atom of Pu-239 you get 207 MeV of energy, so one atom of Plutonium splitting gives off as much energy as 200 of its longer lived decay products decaying.
To get a lot of power from the decay products you start needing a large amount of them because they’re not energy dense and that large amount of them results in lots of gamma rays and handling challenges. Its far far easier to just put them in the ground and add in fresh U-238 that’ll turn into Pu-239 and give off the big chunk of energy.
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