You can not have one without the other. In the case of a taser or other similar devices they can supply a lot of voltage but only in open circuit. As soon as you close the circuit, for example by touching both ends to your body, the power supply in them is not able to sustain the high voltage and the voltage drops to almost nothing. What these devices are rated on is how much energy they can deliver in each pulse. If they keep the energy low enough then it will not cause much harm.
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