There is an exothermic (gives off heat) chemical reaction between the air and the carbon in the logs. The color of the flame (usually yellow in this case) is a good indication of the flame’s temperature.
You are seeing the heat being released by the chemical reaction that shows up as a color of a certain wavelength.
On your gas stove, natural gas and air produce a blue colored flame, which is a higher temperature than the flame produced by the log.
https://maggiemaggio.com/color/2011/08/fire-ii-color-and-temperature/
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