It depends. For most gases there is nothing between them. It is a vacuum.
For liquids and solids intermolecular distances are similar to intramolecular forces. For example in water oxygen’s electrons will have a probability of being between an oxygen nucleus and its own hydrogen nucleus (a covalent bond) and there will be a probability the electron will be between the oxygen nucleus and a neighbouring hydrogen nucleus (a hydrogen bond).
For metals intermolecular and intramolecular electron density is the same since a metal crystal acts as a macromolecule of a visible size.
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