When concrete powder gets wet, it doesn’t just dry out, it undergoes a chemical reaction and becomes a waterproof solid. Some types of concrete can even cure while underwater. Once the chemical reaction is complete, the concrete is “set” and is no longer dissoluble in water. Even if you were to take the set concrete and grind it into a powder similar in appearance to the original uncured concrete, the powdered set concrete wouldn’t “reset”.
Concrete is a mixture of multiple materials, but in modern concrete one of them is usually Portland Cement, which is the material which actually undergoes the chemical reaction causing it to become hard and waterproof. The other ingredients help increase the strength, or add volume and texture. The chemical reactions which cause Portland Cement to cure are very complex and definitely not ELI5-able. Just consider it like a permanent glue, when it is wet you can clean it up, but once it dries it becomes permanently hard and waterproof.
We take rocks and heat them up till they glow red hot. It takes all that heat to chemically separate the water that’s bound in those rocks (clinker) to make cement. Mix that cement with sand for filler and you get concrete. When that concrete gets wet, the cement part of it turns back into the rock stuff it was made from.
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