Photons just bounce around or get absorbed. Sometimes those mother truckers go right on through a molecule. Think visible light through glass. So, when molecules are stimulated by energy they either get physically bumped and spun or the bonds absorb the energy and it vibrates more or the mother trucking said photon goes right through the molecule like idk. In a typical science fashion all of the above usually happens but you have to ask what type of energy is most likely to agitate the molecule and how. Or what frequency of wave whatever you get it
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