This is basically how tempered glass is made, just not quite so maxed out.
You probably could use some sort of container to heat up a piece of glass in a ball shape and then rapidly quench that to get a tail-less Prince Rupert Drop, just this is a lot of work for something with very limited utility where the drawbacks (catastrophic failure without notice) outweigh advantages for anything you’d use it in.
I mean you can, they are called glass marbles.
As much hype there is about the drops being “indestructible” it’s just tempered glass. The prince rupert’s drop is mostly just a neat curiosity because they are easy to make and have a built in vulnerability in the tail that causes them to just explode.
I don’t think there’s anything that prevents creating a completely round prince Rupert drop. It’s just that it would be expensive and difficult to create. One way would be to suspend a marble of glass suspended by jets of heated air until the entire ball reaches the appropriate temperature. Then switch off the jets and have the ball fall into a container of cold water.
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