Saltwater is a natural preservative. When you don’t wear your shoes, they oxidize – a layer of deterioration forms and expands on surfaces, including the soles. Similar to rust, if the rust isn’t removed, the metal is consumed. By wearing your shoes, oxidation is removed by friction and the sweat keeps the material supple.
I am assuming you are talking about leather shoes.
The leather is a natural product, with time the atmosphere dries the leather out slowly (imagine like a piece of bread left on a counter top). The loss of moisture hardens the leather. When you use the shoes, you sweat into the them, this replaces some of the moisture, this is also why you should be polishing your shoes regularly. The polish helps to protect the leather with wax and other products to keep it in a good condition and supple.
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