Friction force = normal force x coefficient of friction
The coefficient of friction is how “rough” the two surfaces are. For steel-on-steel this is very low.
The normal force is how much weight is pressing directly on the surface. For a train this value is immense.
Trains make up for very poor friction by weighing hundreds of tons. That minuscule friction between two steel surfaces on a tiny contact patch is magnified by 40,000 tons and becomes enough to stop a train.
Of course the momentum of the train is also 40,000 tons, so they can’t exactly start and stop on a dime either. They do have relatively poor traction compared to a road vehicle and can’t go up or down steep grades.
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