In general, it’s because your mouth produces less saliva while you sleep. That slightly drier and more importantly less enzymatic environment along with a long period without any rinse (like drinking water during the day would provide) makes a very hospitable environment for bacteria to reproduce. That bacteria feeds on food particles and sugars and produces acids which can harm your tooth enamel, but also produce a strong smell (halitosis). So when you wake up, you’ve got lousy breath.
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