There is a wikipedia page for this! https://en.wikipedia.org/wiki/Coinage_shapes
Short answer: it was not always a circle, for example “Many countries have struck square coins with rounded corners. Some of these, such as the Netherlands zinc 5 cent coin of World War II (1941–1943)[4] and the Bangladesh 5 poisha coin (1977–1994)[5] ”
If you look further in the past, you can see that it was not that round at first: https://en.wikipedia.org/wiki/Coin. But it’s an easy shape to obtain when you either drop some melted metal on a surface, or hit with a hammer on a ductile metal.
That said, Mauryan Empire coins, 3rd century BC, were square coins as well as Bilingual coin of Agathocles of Bactria with Hindu deities, c. 180 BC
Also, rectangular bar of metal that you can cut in was precursor of coins. But it’s nor really “a coin” I would say.
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