We can, it’s just a lot easier to control the process if we use lots of tiny rocks rather than one large one. To make glass that is useful (ie transparent and with the right properties), we need to use ingredients of exactly the right kind, and not all rocks, nor all sand, is suitable. It is easier with sand to make sure what you are putting into the mixture to make the glass is going to have the right composition to get the kind of glass you want out of it.
What do you think sand is? It’s the result of those big rocks being crushed and abraded and sorted until what you have is rather pure quartz, because it’s much harder than the other minerals in the rock. We can do the same thing industrially, but there’s little point when there’s still plenty of glass-grade quartz left. Not to mention the huge amounts of waste that has no particularly productive use given the bulk.
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