Superglue is a brand name of [cyanoacrylate](https://en.wikipedia.org/wiki/Cyanoacrylate) or CA glue, and it is a liquid that becomes a hard plastic when it gets wet. Two pieces of metal are not partially made of water like two pieces of skin are, so the only thing turning the CA hard is the humidity. That takes a lot longer, doesn’t penetrate as far, and the surface area isn’t as large (which is the second biggest thing after moisture content that quickens the process, which is why dots of CA glue is better than a single blob).
As others have said, Superglue is designed to work with moisture, and your fingers have moisture on and in the skin while metal does not.
Fun trivia, Superglue was actually used as a medical adhesive during the vietnam war to seal up gunshot wounds. This is specifically because of how good it is at sticking skin together.
On top of that, your skin is full of tiny pores and has a huge amount of surface-area for the glue to get into and stick to. Metal tends to be smooth, so has a lot less surface to glue, which produces a more brittle connection.
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