Gold is found lying around as pure metal.
Copper can be produced essentially by putting the ore in a wood fire
Iron can be produced by putting the ore in a very hot charcoal fire for a long time and controlling the ratio of fuel to air – tricky but only needs iron age technology
Aluminium requires electricity to extract it from ore (because it’s more reactive than carbon, so we can’t use carbon to remove the oxygen from aluminium oxide) so it couldn’t be produced before we had good control of electricity in the 19th century
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