because ‘stuff’ is what we feel warmth from, and that includes air.
You feel ‘warm air’ because the molecules of the air are excited and transferring that energy to you, or your energy is radiating off to them.
space just doesn’t have any of that stuff to be ‘hot’. There’s practically no molecules to get excited.
It also kinda works in reverse. cooling off in space is difficult because there aren’t other molecules to ‘take’ your energy.
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