Emitting 1 kg of CO2 whilst using 0.2 kg of fuel. Where does that 0.8 kg come from?

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Hi There I didn’t pay much attention in sciences classes I am afraid.
But some one should be able to help me out.
I try to live as consciously as possible and deal with the environment and CO2 emissions. But one thing always stays with me: The volume of CO2.
People always talk about kg CO2 per… For example: diving 5 km in a average car would emit 1kg of CO2. I drive a Toyota Aygo, so a little less then average, but lets say could drive around 20km on 1 litre of fuel. That would mean I’ll use around 0,25 litre for 5 km.
Typical E10 fuel weighs around 0,85kg per litre. That should mean I used around 212 grams of fuel to produce 1kg of CO2. That math doesn’t count up for me… Where does the other 788 grams come from?

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9 Answers

Anonymous 0 Comments

It com from the air.

If the fuel is just fossil fuel it will only contain carbon and hydrogen. To create carbon dioxide you need oxygen to wait is from the air.
If alcohol is mixed in there is some oxygen but let’s assume there is no alcohol.

So the oxygen in the carbon dioxide is from the air, not the fuel and the majority of the mass of CO2 is the oxygen

Gasoline is made of multiple hydrocarbons with slightly different chemical structures but let’s just look at heptane which is one of the main components of gasoline.

The chemical formula is C7 H16. The mass of carbons is 12 and hydrogen is 1 so the molecular mas is 12*7+1*16 = 100. The mass percentage of carbon is 12*7/100=84%

Carbon dioxide is CO2, the mass of oxygen is 16 so the molecular mass is 12+16*2= 44 of that carbon is 12/44=27% So 73% of the mass is from oxygen that the engine gets from the air

So the fuel is 84% carbon by mass but the CO2 is 27% carbon by mass because

The least doing the calculation for 850g of fuel. It contains 850*0.84= 714 grams of carbon. If you but it with oxygen you ger 714/0.27=2644 grams of CO2

You can also calculate the fule you need for 1 kg of CO2 as 1*.27/.84=0.32 kg

CO2 is not the only exhaust water is also produced. Water is 2/18=11% hydrogen bu mass so from 850gram of fuel we get 850*(1-0.84)/0.11 = 1236 grams of water.

The result is that 1 liter of fuel =0.85kg result in 3.88kg of exhaust which is on average 1-0.85/3.88=78% oxygen from the air by mass.

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