Cyanide inhibits the electron transport chain, preventing oxygen from being turned into water. We can just breathe out carbon dioxide, as long as we get enough oxygen. But our cells can only turn oxygen into water when they have enough glucose (or other sugars), which contains enough energy.
This is also why oxygen deprivation is so bad for your brain: your neurons burn a lot of glucose, and won’t stop until they get that sweet, sweet ATP.
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