Metals are not necessarily deep underground. Raw metallic copper existed in surface deposits. Copper and more so iron ores exist on the surface. Pretty much any red rocks probably have some iron content. Red clay does too.
At some point, rocks must have been cooked in a reducing environment like a charcoal furnace, and produced useful metal.
Because not all metal is buried under the ground and requires a substantial effort to extract. Plenty of metal ores can be found above ground. Gold is thought to have been the first metal worked, since it can be found and worked in its pure form. It wouldn’t take much effort to recognize that some types of rocks, when heated, would produce other metals that can also be worked.
Not all metal deposits are buried deep underground, just most of them. It’s entirely possible for ores or even raw metals to be found at the surface level in exposed rock formations. We dig deep to obtain metal ores in the modern day because our demand for metals dwarfs that of primitive societies, and because we exhausted all the large easily-accessible surface-level metal deposits long ago.
This is an exceptional question!
I would assume the ancient’s first encounters with heavy metals would have been with natural river sluices.
Nuggets, pickers and small flakes of lead, gold and iron.
Store them in your leather canteen, accidentally smelt them one day.
Fast forward a few hundred years and your civilization should have realised that the same material is concentrated in veins.
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