Hey! So hormones dont actually work very quickly at all. In fact they move quite slow! Hormones get created in response to certain internal or external stimuli and then shipped through the body via the blood stream. As they move through your body they interact with different areas and cause wide spread responses. Think of them as slow, whole body action grenades. The high speed action molecule you are thinking of is a neurotransmitter.
Neurotransmitters are small molecules that are directly targeted at specifics areas to create instant responses. A good example is seratonin dumps in your brain when something goes happens to you! Cells in your brain will dump large amounts of seratonin or dopamine into the areas between cells ( the synaptic cleft ) and these molecules will bounce around like pinballs dinging receptors that then cause other cells to do the same. These kind of interactions happen really quickly in a target area and tend to have short term effects on your body.
So if your body needs a fast fight or flight type response like being excited by a kiss, it will use neuro transmitters to communicate across cells. If it wants a slow and steady change to the body like increasing muscle it will use an hormone like testosterone that it can ship throughout the body via the blood stream.
Tldr: Hormones are slow, and illicit whole body reactions, neurotransmitters are quick targeted reactions between cells.
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