One method you could use to determine this is to make a compass. Most likely your magnet is too heavy to do this but you can use it to magnetize something light like a pin or paperclip. This you can float on the surface of still water and it will orient itself according to the Earth’s magnetic field. The north pole is negative and the south pole is positive.
Remember that opposite magnetic fields attract and similar repel, so whichever end of the floating compass points north is the positive pole. You would then take your original magnet and see which end attracts that positive end of the pin or paperclip and that would be your magnet’s negative pole.
Of course if you were planning to use your found magnet to make a compass you have sort of gone full circle and needed to already know what you were trying to figure out.
If you have an electron gun (such as an old cathode ray tube), you can examine which way the beam is deflected by the magnet’s field and use that to determine the poles of the magnet. If the beam is pointed to your left, and the north pole of the magnet is placed close to it pointing away from you, the beam will be deflected downward. The south pole will deflect it upward.
This method is interesting because it does not require you to know anything about which way is north (or even be near a planet with a magnetic field at all).
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