This depends on your purpose. In a nuclear bomb or reactor, the neutrons come from other nuclei splitting. The first neutron either comes from a random decay event or from a specialized neutron source.
A few systems to create neutron radiation on-demand exist, too. Nuclear weapons use something which is radioactive in some other kind of radiation, and suddenly combine it with a different element, which is struck by the radiation to free neutrons.
Or you can just perform nuclear fusion. Easy. Not easy to generate electricity from, but easy to do.
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