You can measure Scovilles in a lab these days.
interestingly the Scoville test as was originally created was actually extremely close in calculation when they found the technology to measure it in a lab. The original test was to dilute it in a measured volume until there was no heat. For example Scoville of a million means that 1 part pepper to 1 million parts water is where it is no longer tasted.
So cook a big batch of the chiles of your choice, test it, then add it to your process, whether that is fermenting or whatever. Edit: I would imagine for fermenting it might be done first and then all mixed together and then measured?
Edit I see in another comment you are talking about individual fresh chiles. I imagine they QA for each batch.
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