Your body requires salts to function. Without salts your neurons would cease to signal each other and the cells in your body would stop working.
If you just drunk ultra pure water you would die as it would flush the salts from your body.
The difference between a medicine and a poison is dosage. While sea water is saline and hydration fluids is saline, hydration fluids are 0.9% saline sea water sits around 35%.
There are recommended daily intakes of everything things your body needs including water, sodium, chloride, potassium, glucose, protein, vitamins etc. If you become dehydrated you have been losing mainly sodium and water, therefore both need replacing. Sea water has too much salt, too much salt damages your kidneys among other things.
When enough salt (sodium) is given, other intravenous fluids such as dextrose saline (sugar water) is given, the limits for sugar are much higher than salt so it doesn’t matter so much.
Additionally, giving pure water intravenously is not a good idea because if it doesn’t have enough electrolytes or molecules like sodium or dextrose it can have an osmotic effect i.e. Water will move into the cells rather than stay in the veins where it is needed. This can swell and damage organs. Drinking pure water can cause this too but its less likely.
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