A day is defined as the time between the Sun being in the same position in the sky, and an hour is 1/24th of that. So the clocks stay in sync with the day-night cycle because they’re based on it.
The Earth’s spin on its axis is *not* synced to the day-night cycle. That’s how a single rotation can be less than a complete day long; one complete spin of the Earth doesn’t put the Sun in exactly the same place.
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