When the X-ray bounces off your bones, that light is lost forever. That makes a big ol’ black spot on the image. When the X-ray passes all the way through you, that light is captured. That makes a big ol’ white spot on the image. (There are some parts that make a gradient, like fat. Some of the light went through; some didn’t).
The technician provides the negative; white becomes black, black becomes white. This makes the bones “stand out” in the image. X-ray wavelength is tiny, so a lot of them go through you, and it’s easy to get a good resolution picture.
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