TLDR, English speakers used to say Quixote as quix ote before they knew better leading to quixotic being pronounced as it is today. They have since learned how to say it correctly but words stemming from it are still said as they were.
For those exact words, Quixote is pronounced Key ho te because the work is Spanish and languages will have different pronunciations.
It is pronounced Key Ho Te in English because we know it is a Spanish work and thus pronounce it as a Spanish speaker would.
Quixotic is a layover (a word still around) from when the work was popular before English and Spanish speakers regularly culturally mixed. They read Quixote as quix ote as that is how an English person with only English pronunciations would think it’s said.
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