They changed the Celsius scale to make that work. -273.16°C is absolute zero, by definition. And 0.01°C is the temperature of water at its triple point, by definition.*
Defining the Celsius scale this way is more precise than the classic freezing/boiling point of water definition, since the temperatures at which water freezes and boils can vary depending on several things, in ways that absolute zero and the triple point don’t.
^(*This definition is no longer in use as of 2019. Now, the degree Celsius is defined in terms of absolute zero and the Boltzmann constant, which relates temperature and energy across the universe. But the value we assign that constant was chosen to keep the degree Celsius as close as possible to the prior water-based definition.)
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