Because rice was a staple of most meals, which means people often had a ton of leftover rice. So they created all kinds of dishes to utilize the leftover rice, as not to waste food.
Fried rice, for instance, would get all mushy if you used fresh rice, as there would be too much moisture. Day old rice is more dry, and can hold up to the preparation of the dish.
As others have said, letting the rice sit dries it out and makes it less sticky. Fried rice really does work best with day-old rice, but you can use a variety of rice such as Basmati that has very long grains and is naturally less sticky. Minute Rice and most most microwave pouches also work well. This will subtly change the flavor, but it’s still good.
You can also “hack” Jasmine rice. You rinse it before boiling then cook it like you would cook pasta. Take a cup of rice and boil it for 10 minutes in 2 quarts of water. This method removes almost all of the starch from the outside of the grains, which is what causes it to stick together.
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