A ten pound note is essentially a voucher, issued and guaranteed by the Bank of England, which any merchant will exchange for £10 of goods.
Originally the BoE may have given you £10’s worth of gold, which is “independent” of the currency and valuable across the world. We dropped the gold standard in 1931, and it’s now worth £10 because everyone believes it is.
“Sterling” is actually the name of the currency, and is divided into pounds and pence. The name maybe come from an old Norman coin which had a “steorra”, or star, on it, hence “star-ling”.
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