≡ is a definition. It establishes what a shorter word/symbol/expression means. For example, you might say “x is positive ≡ x>0” to be precise about what you mean by “positive.” Definitions do not require proofs, but you must be careful not to abuse this fact. Simply using ≡ to establish some logical relationship that would be convenient for you is bad practice.
↔ (sometimes also called “if and only if” or “iff”) is a logical relationship that requires proof. For example, you might say that “x is positive ↔ x^3 is positive.” This is not true simply because you said it, but there is a sequence of logical statements (that includes the definition above!) that can show both that the left side implies the right side and that the right side implies the left side.
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