The mustard family has allyl isothiocyanate. The pepper family has piperine. The chile (hot capsicum) family has capsaicin. Szechuan and sancho peppers have sanshools. Mints have menthol.
They’ve all developed to irritate various biological sensors to discourage feeding. Then humans came along, and took it as a challenge.
There’s a molecule call capsaicin.
The body has sensor nerves to detect heat. These nerves work by having holes that open up if it’s hot, letting through charged atoms to cause electrical differences which eventually get sent towards the brain.
Capsaicin gets stuck in the holes and makes them open, so the brain get the hot signal.
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