Atoms exist in different [oxidation states](https://en.wikipedia.org/wiki/Oxidation_state), which gives them different properties. By definition, [elemental is zero](https://chemed.chem.purdue.edu/genchem/topicreview/bp/ch2/oxnumb.html)
Iron in compounds will have different oxidation states, and thus different properties. For example, rust or [iron pyrite](https://en.wikipedia.org/wiki/Pyrite).
https://www.hsph.harvard.edu/nutritionsource/iron/
Iron in the diet is already in compounds that can more readily be reprocessed in digestion.
In a way, your question is similar to “what’s the difference between oxygen in the air and oxygen in water/sugar/rust”.
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