Vector graphics are essentially a program that says, “Draw this shape here, at this size, in this color.” Raster graphics are a picture of that shape, at that spot and size, in that color. If you scale vector graphics, the shape gets redrawn from scratch, like painting a new one on a canvas. If you scale raster graphics, stuff gets pulled, stretched, blurred, and enhanced to arrive at a “best guess” of what the shape would have looked like if it was created with those dimensions in the first place, like stretching a drawing on the surface of a balloon. Things get messed up.
So vector is a better choice on graphics that need precise scaling to any size, but raster is generally superior for paint-like artistic imagery and definitely for photo editing.
Photoshop sort of combines the two through the use of layers, masks, and shapes, but that’s a pretty complicated topic.
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