There are several reasons for this.
First, glass is a much better conductor of heat than plastic, so it can more quickly remove the heat from the hot glass surface on a sunny day. This is important because it helps keep the interior of the car cooler.
Second, glass is much more shatter-resistant than plastic. This is important in the event of an accident, as it helps to protect the occupants of the car.
Finally, glass is a much better optical material than plastic. It transmits light more efficiently and provides a clearer view for the driver.
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