Others have mentioned color for visibility, but to the other part of your question: Absorption and emissivity are related such that things that absorb a wide range of light (e.g. dark clothing) tend to also radiate heat better than a highly-reflective material. This is part of why radiators and heatsinks tend to be coated black rather than left as bare shiny metal; the black finish radiates heat away. The night/dark is generally colder, so it’s more important to prioritize nighttime insulation.
Tl;dr if anything, the antarctic gear should be silvered to minimize its thermal radiation at night, rather than black to maximize daytime heat absorption.
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