Metallurgy.
A lot of early surnames started with tradesmen and described their trades. Smith is the most common English last name because it is part of several professions: blacksmith (working with iron), whitesmith (working with tin), greensmith (working with lead or copper), and brownsmith (working with copper or brass).
Most of these eventually were shortened to either their first or second half, leaving Smith as the most common surname, and Black, White, Green and Brown as relatively common ones.
Edit: whitesmiths are tin
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