Yes, the higher concentration at the source does make the process significantly less unfavorable and that’s how most proposals suggest we do it.
Probably not practical on cars (too much weight), but it makes more sense on things like cement kilns or power plants.
Still tough and costs energy, but a lot better than just going at the bulk atmosphere.
The primary way of capturing CO2 from the atmosphere is condensation. You take in atmospheric air and use cryogenics to cool it down and you remove different gasses as they condense out of the air. Thats not possible for a mobile vehicle and not possible for the quantities that a power plant produces (you’d have to capture the extremely hot air in a tank then give it enough time to condense, not really possible in an open system like a power plant).
Also, its costly and doesn’t make sense for simply removing gasses from the atmosphere. We use this process because we use the various gasses for industrial purposes.
1. Cost. Catching, handling and disposing of all the waste gas is expensive. Put it on a car and, rough guess, 5x the cost of fuel. If it even works.
2. What do we do with it? Remember, we’re taking every atom of carbon we burn and adding 2 oxygen atoms to it. Effectively we have created 200% more waste than input. *We have nowhere to put it all*
3. Wasting even more energy to handle the waste. Gas companies are going to love this.
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