The primary way of capturing CO2 from the atmosphere is condensation. You take in atmospheric air and use cryogenics to cool it down and you remove different gasses as they condense out of the air. Thats not possible for a mobile vehicle and not possible for the quantities that a power plant produces (you’d have to capture the extremely hot air in a tank then give it enough time to condense, not really possible in an open system like a power plant).
Also, its costly and doesn’t make sense for simply removing gasses from the atmosphere. We use this process because we use the various gasses for industrial purposes.
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