With basic chemistry, it is pretty simple to create a 1.5V battery. So you will see many batteries operate on integer multiples of this.
AA/AAA batteries are 1.5V. 1.5*6 = 9V batteries (those big square ones). 1.5*8 = 12V (car batteries and other larger batteries).
12V is just a good medium between “useful” and “low enough power to not have the potential to kill”. It’s also nice to have a low voltage, as you can keep wires (and therefore cost and weight) smaller.
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